Materials science and engineering : Physiochemical concepts, properties, and treaments : Volume 2

M

a

t Volume 2

Physiochemical Concepts, Properties,

and Treatments

Editors

DSc

PhD

PhD

Gennady E. Zaikov,

A. K. Haghi,

Ewa Kłodzińska,

Materials Science

and Engineering

Materials Science

M

and Engineering

a

terials Science and Engineering

Volume 2:

P

h

ysiochemical Concepts, Properties, and

Treatments

Zaiko

v

Haghi

Kłodzińska

Materials Science and Engineering

Volume 2: Physiochemical Concepts, Properties, and Treatments

This book has an important role in advancing non-classical materials on the macro and

nanoscale. The book provides original, theoretical, and important experimental results.

Some research uses non-routine methodologies often unfamiliar to some readers.

Furthermore papers on novel applications of more familiar experimental techniques and

analyses of composite problems are included.

The book includes new research and studies, including on

• the efficiency of gas purification

• the transport properties of films of chitosan-amikacin

• operating conditions of clearing of gas in a rotoklon

• properties and characteristics of varies materials and compounds

• more

About the Editors

Gennady E. Zaikov, DSc, is Head of the Polymer Division at the N. M. Emanuel Institute of

Biochemical Physics, Russian Academy of Sciences, Moscow, Russia, and professor at

Moscow State Academy of Fine Chemical Technology, Russia, as well as professor at Kazan

National Research Technological University, Kazan, Russia. He is also a prolific author,

researcher, and lecturer.

A. K. Haghi, PhD, is the author and editor of 65 books as well as 1000 published papers in

various journals and conference proceedings. Since 1983, he served as a professor at

several universities. He is currently Editor-in-Chief of the International Journal of

Chemoinformatics and Chemical Engineering and Polymers Research Journal and is on the

editorial boards of many international journals. He is a member of the Canadian Research

and Development Center of Sciences and Cultures (CRDCSC), Montreal, Quebec,

Canada.

Ewa Kłodzińska, PhD, is working at the Institute for Engineering of Polymer Materials and

Dyes, Torun, Poland, and investigates surface characteristics of biodegradable polymer

material on the basis of zeta potential measurements. She has written several original

articles, monographs, and chapters in books for graduate students and scientists. Dr. Ewa

Kłodzińska is a member of editorial boards of ISRN Analytical Chemistry and the

International Journal of Chemoinformatics and Chemical Engineering (IJCCE).

___________________________________________________________________

Also available:

Materials Science and Engineering:

Volume 1: Physical Process, Methods, and Models

Editor: Abbas Hamrang, PhD

Reviewers & Editorial Board Members: Gennady E. Zaikov, DSc, and A. K. Haghi, PhD

Hardbound ISBN: 978-1-77188-000-8

Volume 2

Physiochemical Concepts, Properties,

and Treatments

Editors

DSc

PhD

PhD

Gennady E. Zaikov,

A. K. Haghi,

Ewa Kłodzińska,

Materials Science

and Engineering

Materials Science

M

and Engineering

a

terials Science and Engineering

Volume 2:

P

h

ysiochemical Concepts, Properties, and

Treatments

Zaiko

v

Haghi

Kłodzińska

Materials Science and Engineering

Volume 2: Physiochemical Concepts, Properties, and Treatments

This book has an important role in advancing non-classical materials on the macro and

nanoscale. The book provides original, theoretical, and important experimental results.

Some research uses non-routine methodologies often unfamiliar to some readers.

Furthermore papers on novel applications of more familiar experimental techniques and

analyses of composite problems are included.

The book includes new research and studies, including on

• the efficiency of gas purification

• the transport properties of films of chitosan-amikacin

• operating conditions of clearing of gas in a rotoklon

• properties and characteristics of varies materials and compounds

• more

About the Editors

Gennady E. Zaikov, DSc, is Head of the Polymer Division at the N. M. Emanuel Institute of

Biochemical Physics, Russian Academy of Sciences, Moscow, Russia, and professor at

Moscow State Academy of Fine Chemical Technology, Russia, as well as professor at Kazan

National Research Technological University, Kazan, Russia. He is also a prolific author,

researcher, and lecturer.

A. K. Haghi, PhD, is the author and editor of 65 books as well as 1000 published papers in

various journals and conference proceedings. Since 1983, he served as a professor at

several universities. He is currently Editor-in-Chief of the International Journal of

Chemoinformatics and Chemical Engineering and Polymers Research Journal and is on the

editorial boards of many international journals. He is a member of the Canadian Research

and Development Center of Sciences and Cultures (CRDCSC), Montreal, Quebec,

Canada.

Ewa Kłodzińska, PhD, is working at the Institute for Engineering of Polymer Materials and

Dyes, Torun, Poland, and investigates surface characteristics of biodegradable polymer

material on the basis of zeta potential measurements. She has written several original

articles, monographs, and chapters in books for graduate students and scientists. Dr. Ewa

Kłodzińska is a member of editorial boards of ISRN Analytical Chemistry and the

International Journal of Chemoinformatics and Chemical Engineering (IJCCE).

___________________________________________________________________

Also available:

Materials Science and Engineering:

Volume 1: Physical Process, Methods, and Models

Editor: Abbas Hamrang, PhD

Reviewers & Editorial Board Members: Gennady E. Zaikov, DSc, and A. K. Haghi, PhD

Hardbound ISBN: 978-1-77188-000-8

www.appleacademicpress.com

Volume 2

Physiochemical Concepts, Properties,

and Treatments

Editors

DSc

PhD

PhD

Gennady E. Zaikov,

A. K. Haghi,

Ewa Kłodzińska,

Materials Science

and Engineering

Materials Science

M

and Engineering

a

terials Science and Engineering

Volume 2:

P

h

ysiochemical Concepts, Properties, and

Treatments

Zaiko

v

Haghi

Kłodzińska

Materials Science and Engineering

Volume 2: Physiochemical Concepts, Properties, and Treatments

This book has an important role in advancing non-classical materials on the macro and

nanoscale. The book provides original, theoretical, and important experimental results.

Some research uses non-routine methodologies often unfamiliar to some readers.

Furthermore papers on novel applications of more familiar experimental techniques and

analyses of composite problems are included.

The book includes new research and studies, including on

• the efficiency of gas purification

• the transport properties of films of chitosan-amikacin

• operating conditions of clearing of gas in a rotoklon

• properties and characteristics of varies materials and compounds

• more

About the Editors

Gennady E. Zaikov, DSc, is Head of the Polymer Division at the N. M. Emanuel Institute of

Biochemical Physics, Russian Academy of Sciences, Moscow, Russia, and professor at

Moscow State Academy of Fine Chemical Technology, Russia, as well as professor at Kazan

National Research Technological University, Kazan, Russia. He is also a prolific author,

researcher, and lecturer.

A. K. Haghi, PhD, is the author and editor of 65 books as well as 1000 published papers in

various journals and conference proceedings. Since 1983, he served as a professor at

several universities. He is currently Editor-in-Chief of the International Journal of

Chemoinformatics and Chemical Engineering and Polymers Research Journal and is on the

editorial boards of many international journals. He is a member of the Canadian Research

and Development Center of Sciences and Cultures (CRDCSC), Montreal, Quebec,

Canada.

Ewa Kłodzińska, PhD, is working at the Institute for Engineering of Polymer Materials and

Dyes, Torun, Poland, and investigates surface characteristics of biodegradable polymer

material on the basis of zeta potential measurements. She has written several original

articles, monographs, and chapters in books for graduate students and scientists. Dr. Ewa

Kłodzińska is a member of editorial boards of ISRN Analytical Chemistry and the

International Journal of Chemoinformatics and Chemical Engineering (IJCCE).

___________________________________________________________________

Also available:

Materials Science and Engineering:

Volume 1: Physical Process, Methods, and Models

Editor: Abbas Hamrang, PhD

Reviewers & Editorial Board Members: Gennady E. Zaikov, DSc, and A. K. Haghi, PhD

Hardbound ISBN: 978-1-77188-000-8

ISBN: 978-1-77188-009-1

9 781771 880091

90000

MATERIALS SCIENCE

AND ENGINEERING

Physiochemical Concepts,

Properties, and Treatments

Volume 2

MATERIALS SCIENCE

AND ENGINEERING

Physiochemical Concepts,

Properties, and Treatments

Volume 2

Edited by

Gennady E. Zaikov, DSc, A. K. Haghi, PhD,

and Ewa Kłodzińska, PhD

Apple Academic Press

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ABOUT THE EDITORS

Gennady E. Zaikov, DSc

Gennady E. Zaikov, DSc, is Head of the Polymer Division at the N. M.

Emanuel Institute of Biochemical Physics, Russian Academy of Sciences,

Moscow, Russia, and Professor at Moscow State Academy of Fine Chemi￾cal Technology, Russia, as well as Professor at Kazan National Research

Technological University, Kazan, Russia. He is also a prolific author, re￾searcher, and lecturer. He has received several awards for his work, includ￾ing the Russian Federation Scholarship for Outstanding Scientists. He has

been a member of many professional organizations and is on the editorial

boards of many international science journals.

A. K. Haghi, PhD

A. K. Haghi, PhD, holds a BSc in urban and environmental engineering

from University of North Carolina (USA); a MSc in mechanical engineer￾ing from North Carolina A&T State University (USA); a DEA in applied

mechanics, acoustics and materials from Université de Technologie de

Compiègne (France); and a PhD in engineering sciences from Université

de Franche-Comté (France). He is the author and editor of 65 books as

well as 1000 published papers in various journals and conference proceed￾ings. Dr. Haghi has received several grants, consulted for a number of

major corporations, and is a frequent speaker to national and international

audiences. Since 1983, he served as a professor at several universities. He

is currently Editor-in-Chief of the International Journal of Chemoin￾formatics and Chemical Engineering and Polymers Research Journal and

on the editorial boards of many international journals. He is also a member

of the Canadian Research and Development Center of Sciences and Cul￾tures (CRDCSC), Montreal, Quebec, Canada.

vi About the Editors

Ewa Kłodzińska, PhD

Ewa Kłodzińska, PhD, holds a PhD from Nicolaus Copernicus University,

Faculty of Chemistry in Torun, Poland. For ten years, she has been doing

research on determination and identification of microorganisms using the

electromigration techniques for the purposes of medical diagnosis. Cur￾rently she is working at the Institute for Engineering of Polymer Materials

and Dyes and investigates surface characteristics of biodegradable poly￾mer material on the basis of zeta potential measurements. She has written

several original articles, monographs, and chapters in books for graduate

students and scientists. She has made valuable contributions to the theo￾ry and practice of electromigration techniques, chromatography, sample

preparation, and application of separation science in pharmaceutical and

medical analysis. Dr. Ewa Kłodzińska is a member of editorial boards of

ISRN Analytical Chemistry and the International Journal of Chemoinfor￾matics and Chemical Engineering (IJCCE).

CONTENTS

List of Contributors.................................................................................... ix

List of Abbreviations................................................................................ xiii

List of Symbols...........................................................................................xv

Preface ..................................................................................................... xix

1. Theoretical and an Experimental Research of Efficiency of Gas

Purification in Rotoklon with Internal Circulation of a Liquid ............. 1

R. R. Usmanova and G. E. Zaikov

2. Lecture Note on Quantum-Chemical Mechanism and Synthesis of

Selected Compounds................................................................................. 25

V. A. Babkin, V. U. Dmitriev, G. A. Savin, E. S. Titova, and G. E. Zaikov

3. Transport Properties of Films of Сhitosan—Amikacin ........................ 39

A. S. Shurshina, E. I. Kulish, and S. V. Kolesov

4. Research and Calculation of Operating Conditions of Clearing

of Gas in a Rotoklon ................................................................................. 55

R. R. Usmanova and G. E. Zaikov

5. The Effect of the Modification of Silica-Gelatin Hybrid Systems

on The Properties of Some Paper Products............................................ 77

Przemysław Pietras, Zenon Foltynowicz, Hieronim Maciejewski, and Ryszard Fiedorow

6. An Influence of a Size and of the Size Distribution of Silver

Nanoparticles on Their Surface Plasmon Resonance ............................ 93

A. R. Kytsya, O. V. Reshetnyak, L. І. Bazylyak, and Yu. M. Hrynda

7. An Influence of the Kinetic Parameters of the Reaction on a Size

of Obtained Nanoparticles at the Reduction of Silver Ions

by Hydrazine ........................................................................................... 105

A. R. Kytsya, Yu. M. Hrynda, L. I. Bazylyak, and G. E. Zaikov

8. Kinetics and Mechanism of Interaction between Ozone and Rubbers....115

V. V. Podmasteryev, S. D. Razumovsky, and G. E. Zaikov

viii Contents

9. The Intercommunication of Fractal Analysis and Polymeric Cluster

Medium Model ........................................................................................ 131

G. V. Kozlov, I. V. Dolbin, Jozef Richert, O. V. Stoyanov, and G. E. Zaikov

10. Polymers as Natural Composites: Structure and Properties.............. 147

G. V. Kozlov, I. V. Dolbin, Jozef Richert, O. V. Stoyanov, and G. E. Zaikov

11. A Lecture Note on Cluster Model of Polymers Amorphous

State Structure......................................................................................... 203

G. V. Kozlov, I. V. Dolbin, Jozef Richert, O. V. Stoyanov, and G. E. Zaikov

12. Lecture Notes on Quantum Chemical Calculation.............................. 257

V. A. Babkin, G. E. Zaikov, D. S. Andreev, Yu. Kalashnikova, Yu. S. Artemova,

and D. V. Sivovolov

13. Research Methodologies on Physicochemical Properties and

Structure of Graphitic Carbons............................................................. 289

Heinrich Badenhorst

14. The Effect of Antioxidant Compounds on Oxidative Stress in

Unicellular Aquatic Organisms ............................................................. 323

O. V. Karpukhina, K. Z. Gumargalieva, and A. N. Inozemtsev

15. A Lecture Note on Determination of Acid Force of Components

of Synthesis of 1-[2-(О-Acetylmethyl)-3-О-Acetyl-2-Ethyl]-

Methyldichlorinephosphite .................................................................... 331

V. A. Babkin, V. U. Dmitriev, G. A. Savin, E. S. Titova, and G. E. Zaikov

16. Research Methodology on Design and Synthesis of Hydrogel-Based

Supports................................................................................................... 339

D. Horák and H. Hlídková

Index......................................................................................................... 361

LIST OF CONTRIBUTORS

D. S. Andreev

Volgograd State Architect-build University, Sebrykov Department Michurin Street 21, Michailovka,

Volgograd region, Russia

Yu. S. Artemova

Volgograd State Architect-build University, Sebrykov Department Michurin Street 21, Michailovka,

Volgograd region, Russia

V. A. Babki

Volgograd State Architect-Build University Sebrykov Department, 403300 Michurin Street 21, Mi￾chailovka, Volgograd region, Russia, E-mail: [email protected]

Heinrich Badenhorst

SARChI Chair in Carbon Materials and Technology, Department of Chemical Engineering, University

of Pretoria, Lynwood Road, Pretoria, Gauteng, 0002, South Africa, P.O. Box 66464, Highveld Ext.

7, Centurion, Gauteng, 0169, South Africa, Tel.: +27 12 420 4173; Fax: +27 12 420 2516; E-mail:

[email protected]

L. I. Bazylyak

Physical Chemistry of Combustible Minerals DepartmentInstitute of Physical−Organic Chemistry &

Coal Chemistry named after L. M. LytvynenkoNational Academy of Sciences of Ukraine3а

Naukova

Str., Lviv–53, 79053, UKRAINEe–mail: [email protected]

V. U. Dmitriev

Volgograd State Architect-Build University Sebrykov Departament, 403300 Michurin Street 21, Mi￾chailovka, Volgograd region, Russia, E-mail: [email protected]

I. V. Dolbin

Kabardino-Balkarian State University, Nal’chik – 360004, Chernyshevsky st., 173, Russian Federa￾tion, E-mail: [email protected]

K. Z. Gumargalieva

N.N.Semenov Institute of Chemical Physics, RAS, 4 Kosygin Street

H. Hlídková

Institute of Macromolecular Chemistry Academy of Sciences of the Czech Republic, v.v.i. Heyrovský

Sq. 2, 162 06 Prague 6, Czech Republic

D. Horák

Institute of Macromolecular Chemistry Academy of Sciences of the Czech Republic, v.v.i. Heyrovský

Sq. 2, 162 06 Prague 6, Czech Republic, E-mail: [email protected]

Yu. M. Hrynda

Physical Chemistry of Combustible Minerals Department, Institute of Physical Organic Chemistry

and Coal Chemistry, NAS of Ukraine, 3a Naukova Str.Lviv, 79053, E-mail: Ukraineandriy_kytsya@

yahoo.com

x List of Contributors

A. N. Inozemtsev

M. V. Lomonosov MSU, Biological Faculty, Leninskie Gory, 119991 Moscow, Russia, E-mail: olga￾[email protected]

Yu. Kalashnikova

Volgograd State Architect-build University, Sebrykov Department Michurin Street 21, Michailovka,

Volgograd region, Russia

O. V. Karpukhina

N. N. Semenov Institute of Chemical Physics, RAS, 4 Kosygin Street

S. V. Kolesov

The Institute of Organic Chemistry of the Ufa Scientific Centre the Russian Academy of Science,

October Prospect 71, 450054 Ufa, Russia

G. V. Kozlov

Kabardino-Balkarian State University, Nal’chik – 360004, Chernyshevsky st., 173, Russian Federa￾tion

E. I. Kulish

Bashkir State UniversityRussia, Republic of Bashkortostan, Ufa, 450074, ul. Zaki Validi, 32Tel.: +7

(347) 229 96 14, E-mail: [email protected]

A. R. Kytsya

Physical Chemistry of Combustible Minerals Department, Institute of Physical Organic Chemistry

and Coal Chemistry, NAS of Ukraine, 3a Naukova Str.Lviv, 79053, E-mail: Ukraineandriy_kytsya@

yahoo.com

Hieronim Maciejewski

Poznań Science and Technology Park of Adam Mickiewicz University Foundation, Rubież 46, 61-612

Poznań, Poland

Przemysław Pietras

Faculty of Chemistry, Adam Mickiewicz University, Umultowska 89b, 61-614 Poznań, Poland Zenon

Foltynowicz

Faculty of Commodity Science, Poznan University of Economics, Al. Niepodległości 10, 61-875

Poznań, Poland

V. V. Podmasteryev

N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 Kosigin str. Mos￾cow 119334, Russia

S. D. Razumovsky

N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 Kosigin str. Mos￾cow 119334, Russia

O. V. Reshetnyak

Department of chemistry, Army Academy named after Hetman Petro Sahaydachnyi, 32 Hvardiys￾ka Str., Lviv, 79012, Ukraine, Physical Chemistry of Combustible Minerals Department, Institute

of Physical Organic Chemistry and Coal Chemistry, NAS of Ukraine, 3a Naukova Str.Lviv, 79053,

[email protected]

Jozef Richert

Institut Inzynierii Materialow Polimerowych I Barwnikow, 55 M. Sklodowskiej-Curie str., 87-100

Torun, Poland, E-mail: [email protected]

List of Contributors xi

G. A. Savin

Volgograd State Pedagogical University, 40013, Lenin Street, 27, Volgograd, Russia, E-mail: gas￾[email protected]

A. S. Shurshina

Bashkir State University, Russia, Republic of Bashkortostan, Ufa, 450074, ul. Zaki Validi, 32; Tel.: +7

(347) 229 96 14, E-mail: [email protected]

D. V. Sivovolov

Volgograd State Architect-build University, Sebrykov DepartamentVolgograd State Architect-build

University, Sebrykov Departament

O. V. Stoyanov

Kazan National Research Technological University, Kazan, Tatarstan, Russia, E-mail: OV_Stoyanov@

mail.ru

E. S. Titova

Volgograd State Technical University, 40013, Lenin Street, 28, Volgograd, Russia

R. R. Usmanova

Ufa State technical university of aviation, Ufa, Bashkortostan, Russia, E-mail: [email protected];

G. E. Zaikov

Institute of Biochemical Physics Russian Academy of Sciences; 117977 Kosigin Street 4, Moscow,

Russia, E-mail: [email protected]

LIST OF ABBREVIATIONS

Ag–NPs silver nanoparticles

AKDs alkyl ketene dimmers

AM antibiotic amikacin

AMS salts – sulfate

ASA active surface area

ASAs alkenyl succinic anhydrides

ChT chitosan

ChTA chitosan acetate

EDMA ethylene dimethacrylate

GPTSM glycidoxypropyltrimethoxysilane

HEMA hydroxyethyl methacrylate

HVSEM high-vacuum scanning electron microscopy

LVSEM low-vacuum scanning electron microscopy

MS medicinal substance

NM non-modified

NNG natural source

NSG synthetically produced material

Par polyarylate

PB International Paper POL, Poland

PC polycarbonate

PHEMA superporous poly(2-hydroxyethyl methacrylate

PIR piracetam drug form

PMMA poly(methyl methacrylate

PP Hoomark, Ltd., Jędrzychowice, Poland

PPD phenylenediamines

RFL third graphite

SEM scanning electron microscopy

SPR surface plasmon resonances

TEOS tetraethoxysilane

TGA thermogravimetric analyzer

xiv List of Abbreviations

TM Blue Dolphin Tapes, Poland

TZ Kreska, Bydgoszcz, Poland

U740 ethyl silicate

VOF volume of fluid

СSС stretched chains