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Solar cells : Materials, manufacture and operation
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Solar Cells: Materials,
Manufacture and Operation
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Solar Cells: Materials,
Manufacture and Operation
Edited by"
Tom Markvart
University of Southampton, UK and
Luis Castafier
Universidad Politecnica de Catalunya, Barcelona, Spain
ELSEVIER
Elsevier
The Boulevard, Langford Lane, Kidlington, Oxford OX5 1GB, UK
Radarweg 29, PO Box 211, 1000 AE Amsterdam, The Netherlands
First edition 2005
Reprinted 2005, 2006
Copyright 9 2005, Elsevier Ltd. All rights reserved
No part of this publication may be reproduced, stored in a retrieval system
or transmitted in any form or by any means electronic, mechanical, photocopying,
recording or otherwise without the prior written permission of the publisher
Permissions may be sought directly from Elsevier's Science & Technology Rights
Department in Oxford, UK: phone (+44) (0) 1865 843830; fax (+44) (0) 1865 853333;
email: [email protected]. Alternatively you can submit your request online by
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Notice
No responsibility is assumed by the publisher for any injury and/or damage to persons
or property as a matter of products liability, negligence or otherwise, or from any use
or operation of any methods, products, instructions or ideas contained in the material
herein. Because of rapid advances in the medical sciences, in particular, independent
verification of diagnoses and drug dosages should be made
British Library Cataloguing in Publication Data
Solar cells: materials, manufacture and operation
1. Solar cells- Design and construction 2. Solar cells- Materials
I. Markvart, Thomas II. Castafier, Luis
621.3'1244
Library of Congress Cataloging-in-Publication Data
A catalog record for this book is available from the Library of Congress
ISBN-13:978-1-85617-457-1
ISBN-10:1-85617-457-3
For information on all Elsevier publications
visit our website at books.elsevier.com
Printed and bound in Great Britain
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Publisher's Note
In response to a perceived demand for a concise account of solar cell
technology, this volume 'Solar Cells: Materials, Manufacture and Operation'
has been abstracted virtually without change from the 'Practical Handbook of
Photovoltaics: Fundamentals and Applications', also edited by Dr Markvart
and Professor Castafier and published in 2003. (ISBN 185617 3909)
A new chapter on 'Low Cost Industrial Manufacture of Crystalline Silicon Solar
Cells' by Szlufcik et al has been provided as the original chapter was taken from a
proceedings volume and was in need of updating.
To save time and costs, the original Section and Chapter numbering has been
retained, although a new index has been provided.
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Contents
List of Contributors
PART ii SOLAR CELLS
ila Introduction
1 Principles of solar cell operation T. Markvart and L. Castafier
2 Semiconductor materials and modelling T. Markvart andL. Castafier
3 Ideal efficiencies ET. Landsberg and T. Markvart
lib Crystalline silicon solar cells
1 Silicon: manufacture and properties F. Ferrazza
2 Low cost industrial technologies of crystalline silicon solar cells
J. Szlufcik, G, Agostinelli, F. Duerinckx, E. Van Kerschaver and
G. Beaucarne
3 Thin silicon solar cells M. Mauk, P. Sims, J. Rand, and A. Barnett
4 Characterisation and diagnosis of silicon wafers and devices
A. Cuevas and R. Sinton
5 High-efficiency silicon solar cell concepts M.A. Green
iic Thin film technologies
1 Amorphous silicon solar cells D.E. Carlson and C.R. Wronski
2 Microcrystalline silicon solar cells K. Yamamoto
3 Cadmium telluride thin-film PV modules D. Bonnet
4 Cu(In,Ga)Se 2 thin-film solar cells U. Rau and H.W. Shock
lid Space and concentrator cells
1 GaAs and high-efficiency space cells V.M. Andreev
2 High-efficiency concentrator silicon solar cells P.J. Verlinden
lie Organic and dye sensitised cells
1 Photoelectrochemical solar cells A.J. McEvoy
2 Organic and plastic solar cells J. Nelson
ilf Testing, Monitoring and Calibration
1 Standards, calibration, and testing of PV modules and solar cells
C. Osterwald
2 Calibration, testing and monitoring of space solar cells
E. Fernandez Lisbona
viii Solar Cells: Materials, Manufacture and Operation
APPENDICES
Appendix A
Appendix B
Appendix C
Appendix D
Appendix E
Appendix F
Constants, physical quantities and conversion factors
List of principal symbols
Abbreviations and acronyms
Bibliography
International and US standards with relevance to
photovoltaics
Useful web sites, journals and newsheets
EDITORIAL INDEX
List of Contributors
Vyacheslav M. Andreev, Ioffe Physico-Technical
Polytekhnicheskaya str., St. Petersburg 194021, Russia
email: [email protected]
Institute, 26
Allen Barnett, 19 Nivin Lane, Landenberg, PA 19350, USA
email: [email protected]
Dieter Bonnet, Breslauer Ring 9a, D-61381 Friedrichsdorf, Germany
email: [email protected]
David E.Carlson,BP Solar, 989 Corporate Boulevard, Linthicum, MD 21090,
USA
email: [email protected]
Luis Castafier, GDS, Modulo C4 Campus Nord, Universidad Politecnica de
Catalunya, Calle ]ordi Girona 1, 08034 Barcelona, Spain
email: [email protected]
Andres Cuevas, Department of Engineering, Australian National University,
Canberra, Australia 02 O0
email: Andres. Cuevas@faceng. anu.edu, au
Emilio Fernandez Lisbona, Solar Array Section, ESA-Estec, Keplerlaan 1, 2200
AG Noordwijk, The Netherlands
email: [email protected]
Francesca Ferrazza, Eurosolare S.p.A. Via Augusto D'Andrea 6, 00048
Nettuno, Italy
email: francesca.ferrazza@eurosolare, agip.it
Martin A. Green, Centre of Excellence for Advanced Silicon Photovoltaics and
Photonics, University of New South Wales, Sydney NSW 2052, Australia
email: [email protected]
Peter T. Landsberg, Faculty of Mathematical
Southampton, Southampton SO17 1BJ, UK
email: ptl@maths, soton.ac.uk
Studies, University of
x Solar Cells: Materials, Manufacture and Operation
Tom Markvart, School of Engineering Sciences, University of Southampton,
Southampton SO 17 1B], UK
email: [email protected]
Michael Mauk, AstroPower, Inc., 300 Executive Drive, Newark, DE 19702-
3 316, USA
email: [email protected]
Augustin McEvoy, Institute for Molecular and Biological Chemistry, Faculty of
Basic Sciences, Ecole Polytechnique F6d6rale de Lausanne, CH-IO15
Lausanne, Switzerland.
email: [email protected]
Robert P. Mertens, Interuniversity Microelectronic Center (IMEC), Kapeldreef
75,3001 Leuven, Belgium
email: [email protected]
Jenny Nelson, Centre for Electronic Materials and Devices, Department of
Physics, Imperial College, London SW72BW, UK
email: [email protected]
Johan E Nijs, Photovoltech, rue de l'Industrie 52 Nijverheidsstraat, 1040
Brussels, Belgium
email" j ohan.nij [email protected]
Carl R. Osterwald, NREL, 1617 Cole Boulevard, Golden, Colorado 80401-
3393, USA
email: [email protected]
Roger van Overstraeten (deceased), formerly of Interuniversity
Microelectronic Center (IMEC), Kapeldreef 75, Leuven B-3001, Belgium
]ames Rand, AstroPower, Inc., 300 Executive Drive, Newark, DE 19 702-3316,
USA
email: [email protected]
Uwe Rau, Institute of Physical Electronics, University of Stuttgart,
Pfaffenwaldring 47, D-70569 Stuttgart, Germany
email: [email protected]
Hans Werner Schock, Institute of Physical Electronics, University of Stuttgart,
Pfaffenwaldring 47, D-70569 Stuttgart, Germany
email: [email protected]
Contributors xi
Paul Sims, AstroPower, Inc., 300 Executive Drive, Newark, DE 19702-3316,
USA
email: [email protected]
Ronald A. Sinton, Sinton Consulting, Inc., 1132 Green Circle, Boulder, CO
80305, USA
email: [email protected]
Siva Sivoththaman, University of Waterloo, Faculty of Electrical and Computer
Engineering, 200 University Ave, Waterloo, Ontario, Canada N2L 3G1
email: [email protected]
Jozef Szlufcik, Photovoltech, rue de l'Industrie 52 Nijverrheidsstraat, 1040
Brussels, Belgium
email: [email protected]
Pierre J. Verlinden, Origin Energy, GPO Box 1097, Adelaide, SA 5001,
Australia
email: [email protected]
Christopher R. Wronski, 215 Electrical Engineering West, The Pennsylvania
State University, University Park, PA 16802, USA
email: [email protected]
Kenji Yamamoto, Kaneka Corporation, 2-1-1, Hieitsuji, Otsu, Shiga, 520-0104,
Japan
email: [email protected]
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Part !!
Solar Cells
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